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MATERIAL DATA SAFETY SHEET

EPOXY GLAZE

Date of Preparation: 11-08-96

Prepared by: Manufacturer:    LILLY INDUSTRIES, INC
                      Address:    2305 Industrial Road
                                  Dothan, AL 36303

Telephone (334) 794-7555       Night: (334) 794-7555
Emergency (334) 794-7555      Night: (800) 424-9300

 

 

 


 
 

SECTION I PRODUCT IDENTIFICATION

Manufacturer's Code Identification:    EG21 (White Base)
Product Class:    EPOXY POLYAMIDE COATING
Trade Name: EPOXY GLAZE

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HMIS Information:          Health-2*                          Flammability-2
                                       Reactivity-1                       Personal Protective Equipment-X

HAZARD INDEX:         4= Severe      3=Serious       2=Moderate      1= Slight       0=Least
                                       *= Chronic health hazard

Ask your supervisor for specialized handling directions.

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SECTION II HAZARDOUS INGREDIENTS

2-ETHOXYETHYL ACETATE
01                                                       CAS# 111-15-9
% BY WT:       8.000                               APOR PRESSURE: 2.00 MMHG @ 20C

EXPOSURE LIMIT
     ACGIH TLV (TWA)                   5.00 PPM
     OSHA PEL (TWA)                 100.00 PPM
     ACGIH STEL                        150.00 PPM
     Skin notation                                YES

ETHOXYETHANOL
02                                                        CAS# 110-80-5
% BY WT:      7.000                                VAPOR PRESSURE: 4.00 MMHG @ 20C

EXPOSURE LIMIT
     ACGIH TLV (TWA)                  5.00 PPM
     OSHA PEL (TWA)                200.00 PPM
     Skin notation                               YES
           
FORMALDEHYDE
03                                                        CAS# 50-00-0
% BY WT:       .036                                 VAPOR PRESSURE:  22.00 MMHG @ 20C

EXPOSURE LIMIT
     ACGIH TLV (TWA)                    .75 PPM
     OSHA PEL (TWA)                     .75 PPM
     OSHA STEL                           2.00 PPM
     Carcinogen                                  POTENTIAL CANCER HAZARD

TRIMETHYLBENZENE, 1,2,4 ISOMER
04                                                          CAS# 95-63-6
% BY WT:     7.000                                   VAPOR PRESSURE: 4.50 MMHG @ 20C

EXPOSURE LIMIT
     ACGIH TLV (TWA)                25.00 PPM

AROMATIC NAPTHA
05                                                             CAS#64742-95-6
% BY WT:   14.000                                      VAPOR PRESSURE: 10.30 MMHG @20C

EXPOSURE LIMIT
          Supplier Rec. Level          50.00 PPM

XYLENE  ISOMERS
06                                                           CAS#1330-20-7
% BY WT:    1.000                                     VAPOR PRESSURE 6.60 MMHG @ 20C

EXPOSURE LIMIT
          ACGIH (TLV)                100.00 PPM
           OSHA PEL (TWA)         100.00 PPM
           ACGIH STEL                150.00 PPM

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This product contains pigments which may become a dust nuisance when removed
 by abrasive blasting, sanding, or grinding.
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This product contains one or more reported teratogens or suspected teratogens which 
are noted NTP, IARC, or OSHA-Z in the other limits recommended column.

SECTION III PHYSICAL DATA


Boiling Range:        High- 346.0 F                       Low 132.0 F
Vapor Pressure:     See Section II
Vapor Density:     Heavier than air
Evaporation Rate:     Faster than Butyl Acetate
Weight per Gallon:     11.55
% Volatile by Weight:     39.21
Appearance:     N/A
pH:     N/A

Flammability Classification:     Class 2
Actual Flashpoint TCC:     108.0 F
Explosion Level:     Lower .9                 Upper 73.0
Lower Flammability Limit:     N/A

HEAT PROTECTION PROCEDURES
Containers exposed to intense heat from fires should be cooled with water to prevent vapor 
pressure buildup which could result in container rupture.

EXTINGUISHING MEDIA
Use CO2, Dry Chemical, or Foam extinguisher. The National Fire Protection Association
Class B extinguisher is designed to extinguish fires originating from burning liquids.

SPECIAL FIRE FIGHTING PROCEDURES
Water spray may be ineffective. Water may be used to cool closed containers to prevent
pressure buildup and possible autoignition or explosion when exposed to extreme heat.
 If water is used, fog nozzles are preferable.

UNUSUAL FIRE AND EXPLOSION HAZARD
Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open flame.
 Closed container may explode when exposed to extreme heat. Do not apply to hot surfaces.
 Never use welding or cutting torch on or near container (even empty) because product
(even residue) may ignite explosively.

SECTION V HEALTH HAZARD DATA

Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Do not breathe vapors or spray mist. Wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application  unless air monitoring demonstrates vapor/mist levels are below applicable limits. Follow respirator manufacturer's directions for respirator use. This product contains organic solvents which may cause eye, skin, and respiratory tract irritation. They symptoms of exposure are: tearing eyes; redness, drying and cracking of the skin; dizziness, nausea, and fatigue from inhalation; and vomiting from ingestion.  Based on the presence of components (01) chronic overexposure to this material by inhalation or skin contact may cause blood changes; testicular injury; and lung, kidney, liver, and spleen damage.  Overexposure can cause methemoglobinemia and red blood cell damage.  Based on the components (03) this product can be irritating to the eyes.  This mixture contains trace amounts of free formaldehyde which has been designated by ACGIH as an "Industrial substance suspected of carcinogenic potential for man."   Additional formaldehyde may be generated under cure conditions.  Workplace monitoring may be required to determine actual formaldehyde levels.  Based on the presence of components (05) ingestion of this product may result in severe stomach pain, nausea, coma, and even death.  Based on
the presence of (02) studies have shown a possible association with liver damage.  Based on the presence of (03) this product may cause irritation of the upper respiratory tract.  Based on the presence of (03) this product may cause an allergic skin reaction.  Based on the presence of (02) this product may cause skin burns.  This product can be absorbed through the skin causing organ damage. Based on the presence of components (02) this product is ssumed to be moderately toxic.

FIRST AID

EYE CONTACT:
  Flush with luke warm water for 15 minutes. Contact a physician immediately.

SKIN CONTACT: Flush wash with copious amounts of lukewarm water. Remove contaminated clothing promptly. Contact a physician immediately.

INHALATION:
  Remove exposed individual to fresh air.  Restore breathing if required.  Contact a physician immediately.

INGESTION:  Rinse mouth immediately. Give exposed individual 6 to 8 ounces of  liquid.
(Never give anything by mouth to an unconscious person.)  Do not induce vomiting unless advised by a physician. Contact a physician immediately.


SECTION VI REACTIVITY DATA

CONDITIONS TO AVOID
Avoid exposure to sparks, open flame, hot surfaces, and all sources of heat and ignition.  May produce
hazardous fumes when heated to decomposition as in welding.  Fumes may contain carbon monoxide,
carbon dioxide, and oxides of nitrogen.

INCOMPATIBILITY
(Materials to Avoid)  This product is incompatible with strong acids.

HAZARDOUS POLYMERIZATION
Will not occur.

STABILITY
This product is stable.

SECTION VII SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Stay upwind and away from spill unless wearing appropriate protective equipment. Stop and/or contain discharge
if it may be done safely.  Keep all sources of  ignition away. Ventilate area of spill. Use non-sparking tools
for cleanup.   Cover with inert material to reduce fumes.  Keep out of drains, sewers, or waterways.  Contact
fire authorities. Notify local health and pollution control agencies. Call spill response teams if large spill.

WASTE DISPOSAL METHOD
DO NOT FLUSH TO SEWER, WATERSHED, OR WATERWAY
.
Dispose of in accordance with local, state and federal regulations.
Do not incinerate closed containers.

SECTION VIII SAFE HANDLING AND USE INFORMATION

PROTECTIVE EYEWEAR
Avoid contact with eye.  Wear goggles if there is a likelihood of contact with eyes. 
Eyewash stations and safety showers should be readily available in handling areas.
Use safety eyewear with perforated sideshields.

RESPIRATORY PROTECTION
In outdoor or open areas use (NIDSH/MSHA approved) mechanical filter respirator to remove solid airborne
particles of overspray during spray application.  In restricted ventilation  areas use (NIOSH/MSHA approved chemical-mechanical filters designed to remove a combination of particulate and gas and vapor.  In confined
areas use (NIOSH/MSHA approved) air line type respirators or hoods.  Respiratory protection may be necessary
in any later manufacturing operations in which the product may become airborne in the form of vapor or dust.

VENTILATION
Use ventilation as required to control vapor concentrations.  Avoid prolonged or repeated breathing of vapors.
If exposure exceeds TLV, use a NIOSH-approved respirator to prevent overexposure.  Provide general dilution
or local exhaust ventilation in volume and pattern to keep TLV of the most hazardous ingredient in Section II below
acceptable limit, LEL in Section IV below stated limit, and to remove decomposition products during welding or
flame cutting on surfaces coated with this product.

DISCRETION ADVISED
Lilly Industries, Inc. takes no responsibility for determining what measures are required for personal protection
in any specific application.  The general information given should be used with discretion.

PROTECTIVE GLOVES
Required for prolonged or repeated contact.  Wear resistant gloves such as natural rubber, neoprene, buna N or nitrile.
An apron should be worn to avoid skin contact.

HYGIENIC PRACTICES
Wash hands thoroughly before eating and using washroom.  Remove contaminated clothing immediately and
do not wear again until it has been properly laundered.

SECTION IX SPECIAL PRECAUTIONS

HANDLING AND STORING PRECAUTIONS
Keep product containers cool, dry, and away from sources of ignition.  Use and store this product with adequate
ventilation.  Do NOT smoke in storage areas.

Personnel should avoid inhalation of vapors.  Personal contact with the product should  be avoided.
Should contact be made, remove saturated clothing and flush affected skin areas with water. Containers
of this material way be hazardous when emptied.  Since emptied containers retain product residues
(vapor, liquid, and/or solid), all hazard precautions given in this sheet must be observed.

SECTION X SECTION 312 TOXIC CHEMICALS

This product contains the following toxic chemicals subject to the reporting requirements  of section 313 of the
Emergency Planning and Community Right-To-know Act or 1986 and of 40 CFR 372. This information must be included
in all MSDS's; that are copied and distributed for this material.

(* Denotes percent metal contained in the preceding chemical compound)

Chemical   CAS Number  Weight
ETHOXYETHANOL    110-80-5   7.0%
FORMALDEHYDE  50-00-0  .036
1, 2, 4 ISOMER TRIMETHYLBENZENE, 95-63-6                     7.0%
XYLENE ISOMERS 1330-20-7  1.000

THE INFORMATION CONTAINED HEREIN WAS RECEIVED FROM
OUR RAW MATERIAL SUPPLIES AND OTHER SOURCES AND IS BELIEVED TO
BE RELIABLE. THIS DATA IS NOT TO BE TAKEN AS A WARRANTY OR REPRESENTATION
FOR WHICH LILLY INDUSTRIES, INC. ASSUMES LEGAL RESPONSIBILITY.


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