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SECTION
I PRODUCT IDENTIFICATION
Manufacturer's Code Identification:
EG21 (White Base)
Product Class: EPOXY POLYAMIDE COATING
Trade Name: EPOXY GLAZE
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HMIS Information:
Health-2*
Flammability-2
Reactivity-1
Personal Protective Equipment-X
HAZARD INDEX:
4= Severe 3=Serious
2=Moderate 1= Slight
0=Least
*= Chronic health hazard
Ask your supervisor for specialized handling directions.
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SECTION
II HAZARDOUS INGREDIENTS
2-ETHOXYETHYL ACETATE
01
CAS# 111-15-9
% BY WT: 8.000
APOR PRESSURE: 2.00 MMHG @ 20C
EXPOSURE LIMIT
ACGIH TLV (TWA)
5.00 PPM
OSHA PEL (TWA)
100.00 PPM
ACGIH STEL
150.00 PPM
Skin notation
YES
ETHOXYETHANOL
02
CAS# 110-80-5
% BY WT: 7.000
VAPOR PRESSURE: 4.00 MMHG @ 20C
EXPOSURE LIMIT
ACGIH TLV (TWA)
5.00 PPM
OSHA PEL (TWA)
200.00 PPM
Skin notation
YES
FORMALDEHYDE
03
CAS# 50-00-0
% BY WT: .036
VAPOR PRESSURE: 22.00 MMHG @ 20C
EXPOSURE LIMIT
ACGIH TLV (TWA)
.75 PPM
OSHA PEL (TWA)
.75 PPM
OSHA STEL
2.00 PPM
Carcinogen
POTENTIAL CANCER HAZARD
TRIMETHYLBENZENE, 1,2,4 ISOMER
04
CAS# 95-63-6
% BY WT: 7.000
VAPOR PRESSURE: 4.50 MMHG @ 20C
EXPOSURE LIMIT
ACGIH TLV (TWA)
25.00 PPM
AROMATIC NAPTHA
05
CAS#64742-95-6
% BY WT: 14.000
VAPOR PRESSURE: 10.30 MMHG @20C
EXPOSURE LIMIT
Supplier
Rec. Level
50.00 PPM
XYLENE ISOMERS
06
CAS#1330-20-7
% BY WT: 1.000
VAPOR PRESSURE 6.60 MMHG @ 20C
EXPOSURE LIMIT
ACGIH (TLV)
100.00 PPM
OSHA
PEL (TWA) 100.00
PPM
ACGIH
STEL
150.00 PPM
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This product contains pigments which may become a dust nuisance
when removed
by abrasive blasting, sanding, or grinding.
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This product contains one or more reported teratogens or suspected
teratogens which
are noted NTP, IARC, or OSHA-Z in the other limits recommended
column.
SECTION
III PHYSICAL DATA
Boiling Range: High-
346.0 F
Low 132.0 F
Vapor Pressure: See Section II
Vapor Density: Heavier than air
Evaporation Rate: Faster than Butyl
Acetate
Weight per Gallon: 11.55
% Volatile by Weight: 39.21
Appearance: N/A
pH: N/A
Flammability Classification: Class 2
Actual Flashpoint TCC: 108.0 F
Explosion Level: Lower .9
Upper 73.0
Lower Flammability Limit: N/A
HEAT
PROTECTION PROCEDURES
Containers exposed to intense heat from fires should be cooled
with water to prevent vapor
pressure buildup which could result in container
rupture.
EXTINGUISHING
MEDIA
Use CO2, Dry Chemical, or Foam extinguisher. The National Fire
Protection Association
Class B extinguisher is designed to extinguish fires originating
from burning liquids.
SPECIAL
FIRE FIGHTING PROCEDURES
Water spray may be ineffective. Water may be used to cool closed
containers to prevent
pressure buildup and possible autoignition or explosion when
exposed to extreme heat.
If water is used, fog nozzles are preferable.
UNUSUAL
FIRE AND EXPLOSION HAZARD
Keep containers tightly closed. Isolate from heat,
electrical equipment, sparks, and open flame.
Closed container may explode when exposed to extreme heat.
Do not apply to hot surfaces.
Never use welding or cutting torch on or near container
(even empty) because product
(even residue) may ignite explosively.
SECTION
V HEALTH HAZARD DATA
Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage. Intentional misuse
by deliberately concentrating and inhaling the contents may be harmful or fatal.
Do not breathe vapors or spray mist. Wear an appropriate, properly fitted respirator (NIOSH/MSHA
approved) during and after application unless air monitoring demonstrates
vapor/mist levels are below applicable limits. Follow respirator manufacturer's directions for
respirator use. This product contains organic solvents which may cause eye, skin, and respiratory tract
irritation. They symptoms of exposure are: tearing eyes; redness, drying and cracking of the skin;
dizziness, nausea, and fatigue from inhalation; and vomiting from ingestion. Based on the
presence of components (01) chronic overexposure to this material
by inhalation or skin contact may cause blood changes; testicular injury; and lung, kidney, liver, and spleen damage.
Overexposure can cause methemoglobinemia and red blood cell damage. Based on the components
(03) this product can be irritating to the eyes. This mixture contains trace amounts of free
formaldehyde which has been designated by ACGIH as an "Industrial substance suspected of
carcinogenic potential for man." Additional
formaldehyde may be generated under cure conditions.
Workplace monitoring may be required to determine actual formaldehyde levels. Based on the
presence of components (05) ingestion of this product may result in severe stomach pain, nausea, coma, and
even death. Based on
the presence of (02) studies have shown a possible association
with liver damage. Based on the presence of (03) this product may cause irritation of the
upper respiratory tract. Based on the presence of (03) this product may cause an allergic skin
reaction. Based on the presence of (02) this product may cause skin burns. This
product can be absorbed through the skin causing organ damage. Based on the presence of components
(02) this product is ssumed to be moderately toxic.
FIRST
AID
EYE CONTACT:
Flush with luke warm water for 15 minutes. Contact
a physician immediately.
SKIN
CONTACT: Flush
wash with copious amounts of lukewarm water. Remove contaminated
clothing promptly. Contact a physician immediately.
INHALATION:
Remove exposed individual to fresh air. Restore breathing
if required. Contact a physician immediately.
INGESTION:
Rinse mouth immediately. Give exposed individual 6 to 8
ounces of liquid.
(Never give anything by mouth to an unconscious person.)
Do not induce vomiting unless advised by a physician. Contact a
physician immediately.
SECTION VI
REACTIVITY DATA
CONDITIONS
TO AVOID
Avoid exposure to sparks, open flame, hot surfaces, and all
sources of heat and ignition. May produce
hazardous fumes when heated to decomposition as in
welding. Fumes may contain carbon monoxide,
carbon dioxide, and oxides of
nitrogen.
INCOMPATIBILITY
(Materials to Avoid) This product is incompatible with
strong acids.
HAZARDOUS
POLYMERIZATION
Will not occur.
STABILITY
This product is stable.
SECTION
VII SPILL OR LEAK PROCEDURES
STEPS TO BE
TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Stay upwind and away from spill unless wearing appropriate
protective equipment. Stop and/or contain discharge
if it may be done safely. Keep
all sources of ignition away. Ventilate area of spill. Use non-sparking tools
for cleanup.
Cover with inert material to reduce fumes. Keep out of drains, sewers, or waterways.
Contact
fire authorities. Notify local health and pollution control agencies. Call spill
response teams if large spill.
WASTE
DISPOSAL METHOD
DO NOT FLUSH TO SEWER, WATERSHED, OR WATERWAY.
Dispose of in accordance with local, state and federal
regulations.
Do not incinerate closed containers.
SECTION
VIII SAFE HANDLING AND USE INFORMATION
PROTECTIVE
EYEWEAR
Avoid contact with eye. Wear goggles if there is a
likelihood of contact with eyes.
Eyewash stations and safety showers should be readily available in
handling areas.
Use safety eyewear with perforated sideshields.
RESPIRATORY
PROTECTION
In outdoor or open areas use (NIDSH/MSHA approved) mechanical
filter respirator to remove solid airborne
particles of overspray during spray
application. In restricted ventilation areas use (NIOSH/MSHA approved chemical-mechanical filters
designed to remove a combination of particulate and gas and vapor. In confined
areas
use (NIOSH/MSHA approved) air line type respirators or hoods.
Respiratory protection may be necessary
in any later
manufacturing operations in which the product may become airborne
in the form of vapor or dust.
VENTILATION
Use ventilation as required to control vapor concentrations.
Avoid prolonged or repeated breathing of vapors.
If exposure exceeds TLV, use a NIOSH-approved
respirator to prevent overexposure. Provide general dilution
or local exhaust ventilation in volume and pattern to keep TLV of the most hazardous ingredient in Section II
below
acceptable limit, LEL in Section IV below stated limit, and to remove decomposition
products during welding or
flame cutting on surfaces coated with this product.
DISCRETION
ADVISED
Lilly Industries, Inc. takes no responsibility for determining
what measures are required for personal protection
in any specific application. The
general information given should be used with discretion.
PROTECTIVE
GLOVES
Required for prolonged or repeated contact. Wear resistant
gloves such as natural rubber, neoprene, buna N or nitrile.
An apron should be worn to
avoid skin contact.
HYGIENIC
PRACTICES
Wash hands thoroughly before eating and using washroom.
Remove contaminated clothing immediately and
do not wear again until it has been properly
laundered.
SECTION
IX SPECIAL PRECAUTIONS
HANDLING
AND STORING PRECAUTIONS
Keep product containers cool, dry, and away from sources of
ignition. Use and store this product with adequate
ventilation. Do NOT smoke in
storage areas.
Personnel should avoid inhalation of vapors. Personal
contact with the product should be avoided.
Should contact be made, remove saturated
clothing and flush affected skin areas with water. Containers
of this material way be hazardous
when emptied. Since emptied containers retain product residues
(vapor, liquid, and/or
solid), all hazard precautions given in this sheet must be observed.
SECTION
X SECTION 312 TOXIC CHEMICALS
This product contains the following toxic
chemicals subject to the reporting requirements of section 313 of the
Emergency Planning and Community
Right-To-know Act or 1986 and of 40 CFR 372. This information must be included
in all MSDS's;
that are copied and distributed for this material.
(* Denotes percent metal contained in the preceding chemical
compound)
| Chemical
|
CAS
Number |
Weight |
| ETHOXYETHANOL
|
110-80-5
|
7.0% |
| FORMALDEHYDE |
50-00-0 |
.036 |
| 1, 2, 4 ISOMER |
TRIMETHYLBENZENE,
95-63-6
|
7.0% |
| XYLENE ISOMERS |
1330-20-7 |
1.000 |
THE INFORMATION CONTAINED HEREIN WAS RECEIVED
FROM
OUR RAW MATERIAL SUPPLIES AND OTHER SOURCES AND IS BELIEVED TO
BE RELIABLE. THIS DATA IS NOT TO BE TAKEN AS A WARRANTY OR
REPRESENTATION
FOR WHICH LILLY INDUSTRIES, INC. ASSUMES LEGAL RESPONSIBILITY.
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